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Laplace equation in 2D for potential distribution in the thin electrolyte film. Butler-Volmer kinetics at each metal boundary (Au plating, Ni underlayer, SS304 shell, Cu PCB trace). Faradaic dissolution coupled with oxide film growth over hundreds of charge cycles.
A physics-first engineering simulation of vibration-accelerated corrosion in X65 carbon steel pipe under CO2-saturated brine. The system couples: - Damped single-degree-of-freedom structural vibration (SDOF) - Stress-modified Butler-Volmer electrochemical kinetics - Faraday mass loss rate (Corrosion) - Archard fretting wear at pipe supports